Phase Transformation Diagram. PDF filePhase diagram for liquid / liquid phase separation Tc is the critical temperature for the system A B T Homogeneous phase Two phase region 0 %B 100 Tc ∂ ∂ ⎛ ⎝ ⎜ ⎞ ⎠ ⎟ = G P V T − ∂ ∂ ⎛ ⎝ ⎜ ⎞ ⎠ ⎟ = ∂ ∂ ⎛ ⎝ ⎜ ⎞ ⎠ ⎟ = − ∂ ∂ ∂ ∂ ⎛ ⎝ ⎞ ⎠ ⎟ ⎡ ⎣ ⎢ ⎤ ⎦ T G T C V G VK K V G T V V T V T 2 2 2 2 1 =α HNH NH NH=+ + AA AA AB AB BB BB ∂ ∂ ⎛ ⎝ ⎜ ⎞ ⎠.

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PDF fileTherefore phase transformation start at b ie at temperature T S diagram can predict phase transformation information if similar cooling curves had been used during its determination.

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PDF filePhase Diagrams composition of phases At TA= 1320°C Only Liquid (L) present CL= C0 ( = 35 wt% Ni) At TB= 1250°C Both and L present At TD= 1190°C Only Solid ( ) present C = C0( = 35 wt% Ni) C L = C liquidus ( = 32 wt% Ni) C = C solidus ( = 43 wt% Ni) 18 • Rule 3If we know T and Co then we know the amount of each phase (given in wt%).

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18 Rate of Phase Transformation Avrami equation => y = 1 exp (ktn) transformation complete log t Fractiontransformedy Fixed T fraction transformed time 05 By convention rate = 1 / t05 Fraction transformed depends on time maximum rate reached – now amount unconverted decreases so rate slows t05 rate increases as surface area increases &.

Continuous cooling transformation (CCT) diagram

Phase Equilibria Phase Diagrams and Phase Transformations Phase Equilibria Phase Diagrams and Phase Transformations Phase Equilibria Phase Diagrams and Phase Transformations Their Thermodynamic Basis Search within full text Get access Buy the print book Check if you have access via personal or institutional login.

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PDF fileTime Temperature Transformation (TTT) Diagram Below A 1 austenite is unstable ie it can transform into pearlite bainite or martensite The phases finally formed during cooling depend upon time and temperature TTT diagram shows the time required for transformation to various phases at constant.